Solar Cell Tutorial: The New Science of Approaching the Shockley-Queisser Limit
The Shockley-Queisser (SQ) limit for a single junction solar cell is ~33.5 (under the standard AM1.5 flat-plate, solar spectrum). Indeed detailed calculations show that GaAs is capable of achieving this efficiency. Nonetheless, the record GaAs solar cell had achieved only 26.4% efficiency in 2010. Previously, the record had been stuck at 25.1% for almost two decades. Why then the 7% discrepancy between the theoretical limit 33.4% versus the achieved efficiency of 26.4%?