Transport and Recombination in Polymer: Fullerene Bulk Heterojunction Solar Cells
In solar cells, free charge carriers can recombine both via bimolecular (Langevin) and trap-assisted recombination (Shockley-Read-Hall). Trap-assisted recombination of electrons and holes is governed by capture coefficients that are thermally activated with an identical activation energy as measured for the hole mobility μp. To elucidate which recombination mechanism is dominant in organic solar cells, we investigated Charge-transfer (CT) state electroluminescence in several polymer:fullerene bulk heterojunction solar cells.